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991.
《Journal of Coordination Chemistry》2012,65(11):937-945
Reactions of singly-bonded dinuclear complexes [(η5-CH3O2CC5H4)2M2(CO)6] (I, M?=?Mo; II, M?=?W) with the diarenylditelluride [4-CH3C6H4Te]2 in refluxing toluene for 4–6?h afforded dinuclear complexes 1 and 2 trans/ae-[(η5-RC5H4)2M2(CO)4(μ-ArTe)2] (Ar?=?4-CH3C6H4Te). Complexes 1 and 2 were also synthesized by reactions of triply-bonded dinuclear complexes [(η5-CH3O2CC5H4)2M2(CO)4] (III, M?=?Mo; IV, M?=?W) with [4-CH3C6H4Te]2 in refluxing toluene for 1?h. Both complexes have been characterized by elemental analysis, 1H NMR, 13C NMR and IR spectroscopy and X-ray diffraction. Preliminary low-temperature NMR experiments on complexes 1 and 2 have revealed that in solution each complex goes through a rapid inversion of the butterfly four-membered ring M2Te2. 相似文献
992.
993.
《Journal of Coordination Chemistry》2012,65(7):637-641
2,3-Diaminopyridine (H2dap) reacts with (n-Bu4N)[ReOCl4] to form an air-stable salt of composition [ReO(Hdap)2]Cl·2H2O. Spectroscopic studies and X-ray crystallography show that Hdap is coordinated in the monoanionic diamidopyridinium mode to the oxorhenium(V) center. The protonation of the pyridyl nitrogens and the charge on the complex have no influence on the bond lengths and angles, with the rhenium(V)–oxo and average Re–NH bond lengths equal to 1.688(4) and 1.993(5) Å, respectively. 相似文献
994.
《Journal of Coordination Chemistry》2012,65(4):618-626
Two supramolecular complexes, {{Ni(H2O)(phen)2[Au(CN)2]}[Au(CN)2]?·?1.5H2O} n (1) (phen?=?1,10-phenanthroline) and [H2teta][Au2(CN)4]?·?2H2O (2) (teta?=?5,7,7,12,14,14-hexamethyl-1,4,8,11-tetra-azacyocloteradeca-4,11-diene) have been synthesized and structurally characterized. Complex 1 was a one-dimensional infinite chain constructed by [Au(CN)2]? building blocks. In complex 2, there are one cation, one anion, and two water molecules in the asymmetric unit. The two complexes are interconnected through a combination of aurophilic attractions and hydrogen bonds and formed into 3D supramolecular structures. The aqueous solutions of 1 and 2 display interesting luminescence at room temperature. 相似文献
995.
《Journal of Coordination Chemistry》2012,65(8):837-844
Two cobalt complexes [NaCoII(nta)(H2O)] n (H3nta?=?nitrilotriacetic acid) (1) and NH4[CoIII(ida)2]?·?2H2O (H2ida?=?iminodiacetic acid) (2) have been synthesized and characterized by single-crystal X-ray diffraction analysis. Compound 1 crystallizes in the orthorhombic system, space group P212121 with a?=?7.9770(12)?Å, b?=?9.7613(15)?Å, c?=?12.1945(18)?Å, V?=?949.5(2)?Å3, Z?=?4, and R 1?=?0.0705 for 1597 observed reflections. Compound 2 crystallizes in the monoclinic system, space group P2(1)/c with a?=?5.1801(3)?Å, b?=?11.2073(6)?Å, c?=?12.2891(7)?Å, V?=?707.09(7)?Å3, Z?=?2, and R 1?=?0.0349 for 1143 observed reflections. In compound 1, the Co is coordinated by a nitrogen and five oxygen atoms in a distorted octahedral geometry {CoNO5}, and the Na is coordinated by one water molecule and four carboxyl oxygen atoms in slightly distorted square pyramidal geometry. The entire structure shows a three-dimensional network. In compound 2, Co atom is equatorially coordinated by two ida ligands in a distorted octahedral geometry {CoN2O4}. The discrete [Co(ida)2]2? anions are linked by hydrogen bonding to a three-dimensional supramolecular network. 相似文献
996.
《Journal of Coordination Chemistry》2012,65(1):71-76
Crystals of the title complex with diaminobithiazole (DABT) were obtained by a solution diffusion method. X-ray diffraction analysis shows the complex to be monoclinic, space group P21/c with cell dimensions a=11.684(2), b=13.625(2), c=14.859(1) Å and β=109.970(7)°; R=0.026. The Cd(II) atom lies in a distorted octahedral environment with two DABT and two Cl ligands in a cis arrangement. The average internal dihedral angle of 9.3° between thiazole rings of DABT shows the twisted structure of the ligand in the complex. The Cd(II) atom deviates by some -0.570 Å from the mean plane of the thiazole ring containing N(4), but the Cd-N(4) bond is the shortest among four Cd-N bonds in the structure. Intramolecular H-bonds between Cl atoms and amino groups stabilize the cis-configuration of the complex. 相似文献
997.
《Journal of Coordination Chemistry》2012,65(4):275-281
This article reports the synthesis and crystal structures of two new mononuclear Zinc(II) complexes, [Zn2(NTB)2(N3)2](NO3)2·2CH3OH (1) and [Zn2(NTB)2(SCN)2](NO3)2·2CH3OH·H2O (2). Complex 1 crystallizes in the triclinic system, space group P&1macr;, a=13.743(4), b=14.374(4), c=14.443(5) Å; α=77.053(5), β=81.824(5), γ=88.959(6)°; Z=2; R1=0.0418, wR2=0.0889. Complex 2 also crystallizes in the triclinic system, space group P&1macr;, a=12.203(10), b=14.430(12), c=18.541(15)Å; α=72.712(15), β=85.039(15), γ=73.610(14); Z=2; R1=0.0771, wR2=0.1288. In both cases the central zinc(II) metal ions are coordinated to the four nitrogen atoms of NTB and a nitrogen atom of N- 3(1) or SCN-(2) to form distorted trigonal bipyramidal coordination spheres. 相似文献
998.
《Journal of Coordination Chemistry》2012,65(6):711-716
The synthesis of the binuclear complex [(tren)Cu(4,4'-bipy)Cu(tren)] (ClO4)4 where tren = tris(2-aminoethyl) amine and 4,4'-bipy = 4,4'-bipyridine, is described. Single-crystal X-ray diffraction study of the homobinuclear complex shows that two copper(II) ions are bridged by 4,4'-bipyridine and each copper(II) ion is trigonal-bipyramidally coordinated, with tren occupying four sites [Cu-N = 2.030(2), 2.047(2), 2.078(2), and 2.119(2) Å respectively] and a bridging 4,4'-bipyridine in the apical position. The Cu-Cu distance is 11.11 Å. In variable-temperature ESR spectra, the presence of hyperfine structure suggest that some interaction exists between the two copper(II) ions. Temperature-dependent susceptibility studies indicate that it is a weak ferromagnetic interaction with 2J = 1.23 cm-1. 相似文献
999.
《Journal of Coordination Chemistry》2012,65(3):398-408
Two supramolecular compounds based on Keggin polyoxotungstates, (4,4′-H2bpy){[Cu(4,4′-bpy)]2[SiW12O40]} (1) and (4,4′-H2bpy)2[SiW12O40]·2H2O (2) have been synthesized and characterized by elemental analyses, IR, UV, XPS spectra, TG analyses, and single crystal X-ray diffraction analyses. Compound 1 exhibits an infinite 1-D ladder like structure, which is further interconnected into a 3-D supramolecular framework via hydrogen bonding interactions. Compound 2 contains 4,4′-bipyridine (4,4′-bpy), pseudo-Keggin polyoxoanions [SiW12O40]4?, and water molecules. Polyoxoanions together with water molecules in 2 construct a 3-D inorganic supramolecular network through O···O and O···Ow(1) interactions. The electrochemical behaviors and photocatalytic properties of 1 and 2 have been investigated. 相似文献
1000.
《Journal of Coordination Chemistry》2012,65(15):1599-1606
A novel one-dimensional complex salt with the formula [Cd(IM2py)2][Au(CN)2]2 (IM2py?=?2-(2′-pyridinyl)-4,4,5,5-tetramethylimidazoline-1-oxyl), has been synthesized and its structure was determined by single-crystal X-ray diffraction methods. The coordination geometry around Cd(II) ion is a distorted octahedral. IM2py coordinates to Cd(II) via pyridyl- and imino-N atoms to form a planar, five-membered chelate ring. [Cd(IM2py)2][Au(CN)2]2 units are linked through weak Au?···?Au interactions, generating an infinite 1D zigzag chain. Magnetic studies show weak antiferromagnetic coupling between two radicals through the diamagnetic Cd(II) ion. 相似文献